diff --git a/input/kinetics/families/Birad_R_Recombination/groups.py b/input/kinetics/families/Birad_R_Recombination/groups.py index 10073461f9..e0c8b1f634 100644 --- a/input/kinetics/families/Birad_R_Recombination/groups.py +++ b/input/kinetics/families/Birad_R_Recombination/groups.py @@ -1019,3 +1019,20 @@ """, ) +forbidden( + label = "trioxidanyl", + group = +""" +multiplicity [2] +1 *2 O u1 p2 c0 {2,S} +2 *1 O u0 p2 c0 {1,S} {3,S} +3 O u0 p2 c0 {2,S} {4,S} +4 H u0 p0 c0 {3,S} +""", + shortDesc = u"""""", + longDesc = +u""" +Forbid this species because it decays and gives you [O] + [O]O <=> O2(singlet) + OH +even if you have forbidden singlet O2 in your mechanism +""", +) diff --git a/input/kinetics/families/R_Recombination/groups.py b/input/kinetics/families/R_Recombination/groups.py index 57c9859a4c..123e0ef2f7 100644 --- a/input/kinetics/families/R_Recombination/groups.py +++ b/input/kinetics/families/R_Recombination/groups.py @@ -2782,3 +2782,21 @@ """, ) + +forbidden( + label = "trioxidanyl", + group = +""" +multiplicity [2] +1 O u1 p2 c0 {2,S} +2 * O u0 p2 c0 {1,S} {3,S} +3 * O u0 p2 c0 {2,S} {4,S} +4 H u0 p0 c0 {3,S} +""", + shortDesc = u"""""", + longDesc = +u""" +Forbid this species because it decays and gives you O2 + OH <=> O2(singlet) + OH +even if you have forbidden singlet O2 in your mechanism +""", +)